Moderate and high pressure boilers require both external pretreatment and internal treatment. Also sudden load changes can allow temporary high dissolved oxygen levels. Basic water treatment of steam boilers steve kenny and dave pope chemco water technology vancouver, wa this is a brief discussion on lowpressure steam boiler chemistry. The natural bicarbonate alkalinity is not removed in a sodium exchange water softener.
Highpressure steam cycle and boiler water treatment. Water treatment requirements for low and medium pressure. Association of water technologies technical manual 7. Mar 21, 2016 the basis of effective industrial boiler water chemistry control is normally well understood, but when carried out incorrectly leads to avoidable increases in operating costs, plant pressure. Carryover is a function of drum pressure and therefore is more important at high steam pressures. What is a boiler feed water treatment system and how does. Operation limits of boiler feed water and boiler water, when congruent phosphate treatment was used. Very high pressure boilers, from above 1200 psig to supercritical pressures. Water treatment boiler water treatment where the silica content is high, or if feed water is taken from cement washed tanks. Discusses potential chemistry control problems that can lead to furnace tube corrosion. If feed water temperature is below 140f it also requires an oxygen scavenger. Highpressure boilers usually have areas of high heat flux and feedwater, composed of demineralized makeup water and a high percentage of condensate returns. Explain the process of a redox titration and the use of an indicator to determine the endpoint. The international association for the properties of water.
Nalco addresses water conditions related to hardness, oxygen, silica, iron and more. The higher the operating pressure of the boiler, the more critical the removal of. Low and medium pressure boilers must be protected from scale deposition and corrosion to promote optimum energy efficiency and prolong the useful life of the plant equipment. The basis of effective industrial boiler water chemistry control is normally well understood, but when carried out incorrectly leads to avoidable increases in. Only relatively wide ranges can be given as to maximum levels of alkalis, salt, silica. Although not widely used in the united states, inferred ph is popular in europe.
Boiler chemical cleaning and treatment selection consist of following stages ex. Water steam cycle in a high pressure, conventional drumtype plant. May 05, 2015 also high concentrations of deposits cause corrosion. An understanding of the fundamentals of boiler water chemistry is essential to the power engineer who continually strives to increase the efficiency of the boilers and steamusing equipment. The pressure and design of a boiler determine the quality of water it requires for steam generation. Corrosion produces solid metallic oxides and hydroxides which are carried away by the system flow to be deposited at another place. Feedwater purity requirements therefore can vary widely. Feed water purity requirements therefore can vary widely. Nonvolatile components of the treatment are consumed by contaminants in the feedwater.
Any boiler operating at a pressure higher than 15 psi is considered a highpressure boiler. High pressure boiler water treatment free download as pdf file. Boiler feed water boiler water drum pressure psi iron ppm fe copper ppm cu total hardness ppm caco3 silica ppm sio 2 total alkalinity. If you went into a boiler room and the fire was on, and there was not water in the boiler, you should immediately add water to the boiler. Whether distilled or raw city water is used for boiler makeup, chemical treatment is. Used to control transient heat migration can be used as a feed water tank and feed the boiler in lieu of the da can be an integral part of the da two. A low pressure firetube boiler can usually tolerate high feed water hardness with proper treatment while virtually all impurities must be removed from water used in some modern, high pressure boilers. For industrial companies using a boiler for its facility, some type of boiler feed water treatment system is usually necessary to ensure an efficient process and quality steam generation. Water treatment for high pressure boilers in sugar plant.
Sep 26, 2016 a boiler feed water treatment system is a system made up of several individual technologies that address your specific boiler feed water treatment needs. Details related to boiler water chemistry can be found in chapter v of power plant instrumentation and control handbook. The most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime, expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the. A boiler is an appliance designed to heat water and produce energy.
Pdf concentration control of silica in water chemical regime for. High pressure boiler water treatment steam corrosion scribd. Even with sulfite feed to the deaerator, but especially if sulfite is fed to the boiler, the. In a fire tube boiler the water flows through the tubes. Although dealkalization of boiler makeup is a common practice in high pressure boiler installations, many low and medium pressure boilers operate on soft water makeup. The water that is actually in use within the boiler is called boiler water. Asme guidelines for water quality in modern industrial water tube boilers for reliable continuous operation. Apr 27, 2015 this can be done by ion exchange dealkalization or demineralization. The boiler water and boiler feed water were analyzed regularly as a part of monitoring program, a typical operation limits of the second period are shown in table 1. Any of the above forms of corrosion or erosion can cause shortened boiler tube life.
The definition of low and medium pressure is somewhat discretionary. Whereas hot water systems will normally operate at boiler pressures between 50 kpa and 300400 kpa, high pressure hot water systems are used for industrial applications with pressures up to 20002500 kpa. The heat is applied to water in an enclosed container before being distributed throughout the system. The major difference between a lowpressure and a highpressure boiler is the amount of pressure per square inch and pounds per square inch gauge that the boiler produces. Details related to boiler water chemistry can be found in c. Boiler water phosphate chemistry phosphate highpressure drumtype. For drum operating pressure kgcm2 g 61100, 101165, and 166205 with po4 treatment type of boilers. This will cause pitting unless the valve and the t are replaced with stainless steel. Small amount of boiler water drawn off near surface continuously or intermittently function is to control concentration of dissolved solids.
Chemistry 224 the condensate, feedwater and boiler system. The boiler construction is as for steam boilers, but the water line is held higher and the pipe system is. Boilers in which steam produced at or above 70 bar psi subcritical, below critical pressure 225 kgcm2, drum type boilers. In certain cases, when row water is evaporated and is high in silica, carryover may admit silica into the distilled water system. Extensive analyses of different parameters of boiler water chemical regime wcr of. Lets take a look at the boiler water chemistry and the effects resulting from the inability of maintaining the correct chemical equilibrium of the various properties.
Hence feed water is to be very pure for high pressure boilers. Properly treat boiler water for efficient, long term operation. Describes the problem and provides recommendations for correctingpreventing the issue. Chemical regime in water quality management of high. The water used in high pressure steam plants is commonly treated with small. Difference between low and highpressure boilers hunker. The deposit coating retards the flow of heat from the furnace gases into the boiler water. For the purposes of this discussion, low pressure shall apply to boilers up to 150 psig.
Removes boiler water with a high concentration of solids which is. If p t2, usually the case for boiler water chemistry. Inferred ph in steam plant water chemistry monitoring introduction background inferred ph means ph calculated from straight and cation conductivity. Mineral salt contaminants enter the system through condenser tube leaks and atmospheric carbon. The calculation can be applied to condensate, feedwater, and boiler water. Determine the ph of boiler water from a nitric acid titration and the emergency ph table. Because of these conditions, highpressure boilers are prone to caustic attack. Boiler water chemistry properties of feed water explored.
Example p alk 300, t alk 400 ppm oh 2pt 2 x 300 ppm 400 ppm 200 ppm as hydroxyl alkalinity. Inferred ph in steam plant water chemistry monitoring emerson. Boiler water treatment introduction a boiler is a closed vessel in which water under pressure is transformed into steam by the application of heat. Hot alkaline treatment selection, solventacid cleaning selection hydrochloric acid, citric acid, ethylenediaminetetraaceticacid edta, sulfuric acid, sulfamic acid, and highpressure water jetting hpwj. The first priority is to minimize the amount of makeup water. Alkalinity control engineering solutions for water. Boilers vary widely in size from small, portable or shopassembled units to large furnaces. In this case, you have water that has alkaline ph, which has neutralized the hydrogen ion, preventing bicarbonate ions from being present in the water. Treating boiler feed water is essential for both high and low pressure boilers. Most low pressure boiler system operators monitor boiler water alkalinity because it correlates very closely with ph, while most feedwater, condensate, and high pressure boiler water requires direct monitoring of ph. A boiler is a vessel in which water is heated under pressure and vaporized into steam for a specific purpose. The following are specified limit for high pressure boiler from different organization. Control of boiler water chemistry, before and after the water enters the steam generating system, is vital to efficient operation, acceptable maintenance costs, and satisfactory equipment. It is important to note that the small tubes in the watertube boiler can withstand high pressure better than the large vessels of a iretube boiler.
Most highpressure and large boilers are of this type figure 9. What is a boiler feed water treatment system and how does it. Triad highly recommends that boiler feed water be treated before it enters the boiler. This, in turn, necessitates high purity for makeup water. The pressure and design of a boiler determine the quality of. Water treatment requirements for low and medium pressure boilers. The guidelines for water quality control of watersteam in boiler plants of 60 kgcm2 and above are furnished as recommended by many boiler designers. The highpressure boilers are widely used for power generation in thermal power plants.
Rather, like many boiler chemi cals, it has a limited stability that does not preclude its use in boilers. Iron rusts rapidly in the presence of oxygen and moisture a nd very rapidly when the partial pressure of oxygen is high or when the temperature is high. In field studies feeding h edp or pbtc, there has always been a residual found, even when being applied at 800 psig and at 20 cycles of concentration. Demineralisation can only produce acceptable makeup quality for high pressure boilers of the order of specific electrical conductivity less than 0. Foaming and carryover are caused due to high dissolved solid and caustic alkalinity in combination with leakages, load changes and organic matter oil. Boiler water treatment chemicals, feed, and control. In modern intermediate and higher pressure boilers with heat transfer rates in excess of 200,000 btuft 2n 5000 calm hr, the presence of even extremely thin deposits will cause a serious elevation in the temperature of tube metal.
Priming foaming boiler water superheaterreheater piping attemperation water high pressure boiler definition terminology. In low pressure boilers internal treatment may be the only treatment necessary because much of the condensate is returned and the raw water is of good quality. Water treatment recommendations vary depending on the operating pressure of the boiler, the application steam or. Explain the use of buffers in boiler water treatment. In the boiler furnace, the chemical energy in the fuel is converted into heat, and it is the function of the boiler to transfer this heat to the contained water in the most efficient manner. Explain the process of an acidbase titration and the use of ph indicators. When steady flow of feedwater is established through the economizer, put the water side of the highpressure feedwater heaters into service.
Basic water treatment of steam boilers steve kenny and dave pope chemco water technology vancouver, wa this is a brief discussion on low pressure steam boiler chemistry. Controlling the ph of water is the first step towards boiler treatment. Using of congruent phosphate as equilibrium phosphate boilers. Temperature and corresponding pressure affect stability. Differential pressure regulator boiler air vent 2 pipe primary. Most lowpressure boiler system operators monitor boiler water alkalinity because it correlates very closely with ph, while most feedwater, condensate, and highpressure boiler water requires direct monitoring of ph. Applications of chemistry, water treatment webpage. Solid treatment chemicals are fed only to boiler water, never to condensate and.
It was general practice to install zinc plates andor alkaline chemicals to reduce corrosion within the boiler. With rise of steam pressure and flow it is necessary to feed water to boiler continuously. The evolution of power plant watersteam chemistry power. High pressure boiler chemistry boiler corrosion free. Therefore, the higher the pressure, the more chemical treatment is concentrated outside the boiler in water preparation chapter 2, and the less internal boiler water treatment and condensate treatment is required. Boiler pressure plays an important part in mechanical carryover, as the density of water and steam approach unity as the pressure approaches the critical point of 3208 psia. Boiler water treatment chemical guidelines part ii. According to gaylussacs law of pressuretemperature, the.
Thus, information is required on the volatility of the salts and their corresponding acids. Boiler chemistry control and treatment of feed water. Provides a boiler water chemistry that allows for the. In a water tube boiler the fire passes through the tubes.
Boiler water treatment chemicals, feed, and control perhaps. In a highpressure boiler, if the feedwater pressure increases, the saturation temperature of water rises and the latent heat of vaporization decreases. Industrial boiler water treatment and chemistry an. A successful water treatment approach requires a total system approach to. High pressure water lancing or chemical cleaning are methods.
Eliminates chemistryrelated damage in highpressure piping, boilers, and turbines. Copper deposits are a serious problem on new highpressure boilers. Using of congruent phosphate as equilibrium phosphate. A lowpressure firetube boiler can usually tolerate high feedwater hardness with proper treatment while virtually all impurities must be removed from water used in some modern, highpressure boilers. Inferred ph in steam plant water chemistry monitoring. The international association for the properties of water and. Therefore, the higher the pressure, the more chemical treatment is concentrated outside the boiler in water preparation chapter 2, and the less internal boiler water treatment and condensate treatment is. Properly treat boiler water for efficient, long term. Shoreside high pressure systems experienced failures from localized caustic concentrations in 1930s and 1940s excess hydrate alkalinity led to metal damage in the form of caustic embrittlement cracking or gouging new boiler water treatment was developed using the alkalinity derived from phosphate alone, eliminating sodium. Example p alk 300, t alk 400 ppm oh 2pt 2 x 300 ppm. If the condensate contains oxygen, intermittently high dissolved oxygen levels in the feedwater may occur. Feedwater is continuously mixed with treated boiler water in the steam drum and descends through downcomer tubes into the lower sections of the boiler and into the mud drum. It provides dry kiln boiler operators the tools to maintain an efficient and effective boiler chemistry program.
The benchmarking process or other means of unit assessment should be repeated periodically as a means of checking the overall impact of improvements. It works as an antiscalant since phosphate react with calcium hardness to create suspended solids which is easier to discharge via blowdown in order to prevent any calcium carbonate caco3 calcium. Maintenance of proper ph throughout the boiler feedwater, boiler, and condensate systems is essential for corrosion control. During the early development of boilers, water treatment was not so much of an issue, as temperatures and pressures were so low that high amounts of scale and rust would not form to such a significant extent, especially if the boiler was blown down. As a general rule, the higher the boiler pressure, the higher the quality of feedwater required.
One of the disadvantages of this treatment is that, on highpressure drum type units, the detectable concentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and then return to the original levels on subsequent load or pressure reductions. Alkalinity control engineering solutions for water management. Water treatment recommendations vary depending on the operating pressure of the boiler, the application steam or hot water, and other parameters. Also high concentrations of deposits cause corrosion. A boiler is called a highpressure boiler when it operates with a steam pressure above 80 bars. The major difference between a low pressure and a high pressure boiler is the amount of pressure per square inch and pounds per square inch gauge that the boiler produces. A guide to thermal power plants here only treatment part is discussed, with special reference to supercritical boilers. High pressure boiler chemistry boiler corrosion free 30. There are several different kinds of boilers, heated by coal, solid fuel, oil or gas. The water in the boiler should have a ph level of between 7. Boiler water phosphate chemistry phosphate high pressure drumtype utility boiler psb25 created date.